We search for the production of Technicolor particles in $\rm e^+e^-$ collisions at the highest centre-of-mass energies at LEP. The results are based on data collected by the OPAL detector in the year 2000 at ${\sqrt{s} \approx}$ 200\,--\,209\,GeV corresponding to an integrated luminosity of 209.4\,pb$^{-1}$. In particular, we search for the processes $\rm e^+e^-\rightarrow\rho^0_T/\omega^0_T\rightarrow\pi^+_T\pi^-_T\rightarrow b\bar{q}\bar{b}q^\prime$ and $\rm e^+e^-\rightarrow\rho^0_T/\omega^0_T\rightarrow\pi^0_T\gamma\rightarrow b\bar{b}\gamma$. No excess over the expectation from Standard Model processes has been observed. We derive upper limits for the production cross-sections as a function of the technipion mass $m_{\pi_{\rm T}}$. The results are interpreted within the Technicolor Straw Man Model and exclusion regions in the ($m_{\rho_{\rm T}/\omega_{\rm T}},m_{\pi_{\rm T}}$) plane are derived. An absolute lower limit on the $\pi_{\rm T}$ mass is set to 62\,GeV at 95\% CL, independently of other parameters in the Technicolor Straw Man Model.